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It’s been really hot here all day long (1000 + through the day) and tonight while heading home I turned the A/C off and within a couple of minutes the Sorento’s windows fogged (Steamed) over real quick but evaporated just as quickly. Could this be a heater core problem?
 

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I would imagine that it's just condensation and humidity adjusting in the car (windows open?) to the ambient weather conditions. The through flow of air will account for rapid clearing, the effect of hot air condensing on colder surfaces will account for the misting.

What altitude you are at will have an effect too, I was in Singapore earlier this year on the 32 floor of a hotel, the air conditioning in the room created condensation outside that lasted all day.
 
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